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Hydrogen diffusion and solubility in vanadium modified

The Purification of Hydrogen Johnson Matthey Technology

The purification or separation of hydrogen has traditionally been based on solid-state diffusion technology utilising noble metal membranes.The development of this technology,which has been centred around improved diffusion membrane materials based on the silver-palladium alloy system,is reviewed in this paper.It is shown that,despite the emergence of alternative techniques,diffusion Some results are removed in response to a notice of local law requirement.For more information,please see here.Previous123456NextHydrogen Diffusivity and Electrolyte Permeability of the Nov 30,2019 Hydrogen diffusion and solubility in vanadium modified#0183;The diffusion coefficient of hydrogen in KOH is reported as a function of molarity and temperature,26 while data for the hydrogen solubility in KOH could only be found for 30 Hydrogen diffusion and solubility in vanadium modified#176;C.27 Based on these reported values,the hydrogen diffusivity in KOH was calculated for 30 Hydrogen diffusion and solubility in vanadium modified#176;C for the different KOH concentrations used in this study.Some results are removed in response to a notice of local law requirement.For more information,please see here.12345NextSolubility and diffusion of hydrogen in vanadium-oxygen The solubilities and diffusion coefficients of hydrogen have been measured in vanadium-oxygen alloys.A small increase in the isopiestic solubility of hydrogen at 297 and 373 K was caused by the addition of oxygen to vanadium,but Sieverts law was obeyed in each alloy in the hydrogen concentration ranges studied.Hydrogen diffusion coefficients as a function of hydrogen concentration were

Some results are removed in response to a notice of local law requirement.For more information,please see here.Solubility and diffusion of hydrogen in vanadium-oxygen

The solubilities and diffusion coefficients of hydrogen have been measured in vanadium-oxygen alloys.A small increase in the isopiestic solubility of hydrogen at 297 and 373 K was caused by the addition of oxygen to vanadium,but Sieverts law was obeyed in each alloy in the hydrogen concentration ranges studied.Hydrogen diffusion coefficients as a function of hydrogen concentration were SOLUBILITY OF HYDROGEN IN STAINLESS STEEL (Journal@article{osti_4271744,title = {SOLUBILITY OF HYDROGEN IN STAINLESS STEEL},author = {Blanchard,R},abstractNote = {The solubility of hydrogen in 18-8 stainless at 700 to 1000 C varies from 5.5 to 7.25 cm/sup 3//100 g.The addition elements (Mo and Nb) cause a small decrease of tbe solubility.

Quantitative Evaluation of Hydrogen Solubility and

A concept for alloy design of hydrogen permeable membrane with high hydrogen permeability and long-term durability has been proposed in view of the PCT factor,f PCT,and the ductile-to-brittle transition hydrogen concentration,DBTC.As an example,V10mol%Fe alloy has been designed for low operative temperature,which exhibits excellent and stable hydrogen permeability for at least 1000 Prediction of hydrogen permeability in VAl and VNi Mar 01,2013 Hydrogen diffusion and solubility in vanadium modified#0183;The hydrogen solubility in each alloy was estimated from the CALPHAD thermodynamic calculation.Then,the calculated diffusion coefficient and the solubility of hydrogen were combined to finally predict the hydrogen permeability in the VAl and VNi alloys as a functional form of alloying element content.Origin of hydrogen trapping site in vanadium carbide May 30,2020 Hydrogen diffusion and solubility in vanadium modified#0183;A comparison of the solubility of hydrogen in different sites shows that hydrogen will tend to segregate towards the ironvanadium carbide interface and that carbon vacancies within a vanadium

KR101493473B1 - Vanadium-based hydrogen permeation

A vanadium-based hydrogen permeable alloy for a separator,a method for producing the same,and a method of using the separator using the same are provided.The vanadium-based hydrogen-permeable alloy for separator contains nickel (Ni) of greater than 0 and less than 5 at%,iron (Fe) of 5 at% to 15 at%,yttrium (Y) of greater than 0 and less than 1 at% and remaining vanadium and impurities do.KR101493473B1 - Vanadium-based hydrogen permeationA vanadium-based hydrogen permeable alloy for a separator,a method for producing the same,and a method of using the separator using the same are provided.The vanadium-based hydrogen-permeable alloy for separator contains nickel (Ni) of greater than 0 and less than 5 at%,iron (Fe) of 5 at% to 15 at%,yttrium (Y) of greater than 0 and less than 1 at% and remaining vanadium and impurities do.Images of hydrogen diffusion and Solubility in vanadium Mo imagesThermodynamic properties in the systems vanadiumSolubility and diffusion of hydrogen in vanadium-oxygen alloys.Metallurgical Transactions A 1988,19 (1) ,67-72.DOI 10.1007/BF02669815.D Steinbinder,H Wipf,G Kearley,A Magerl.On the superdiffusion of hydrogen in vanadium.

Hydrogen trapping in T24 Cr-Mo-V steel weld joints

Hydrogen-assisted cracking is a critical combination of local microstructure,mechanical load and hydrogen concentration.Welded microstructures of low-alloyed creep-resistant Cr-Mo-V steels show different hydrogen trapping kinetics.This influences the adsorbed hydrogen concentration as well as the diffusion by moderate or strong trapping.A common approach to describe hydrogen traps is by Hydrogen permeation characteristics of vanadiumFor example,for pure vanadium [1] such ratio could be reached at T = 673 and at hydrogen pressure 410 4 Pa,while in lower temperature region this pressure reduces significantly and at Hydrogen in Steels : Total Materia ArticleBecause of the hydrogen solubility decreases with a decreasing temperature,there will be a build up of H 2 pressure in the steel matrix during rapid cooling.For the limiting case of no hydrogen diffusion,the H 2 pressures will be as shown below in the steel containing 2,4 and 8 ppm H.

Hydrogen in Steels IspatGuru

Dec 11,2014 Hydrogen diffusion and solubility in vanadium modified#0183;Hydrogen solubility in steel.The unit used to express H content in steel is parts per million (ppm) and milli litres or cubic centimeters of H per 100 gm of steel corrected to standard temperature and pressure.The relationship between the two units is 1 ppm = 1.11 ml/100 gm.Hydrogen diffusion and solubility in vanadium modified @article{osti_7030745,title = {Hydrogen diffusion and solubility in vanadium modified pressure vessel steels},author = {Brouwer,R C},abstractNote = {In the petrochemical industry,reaction conditions in hydrogen conversion reactors are shifting to higher temperatures and higher hydrogen pressures.The presently used thick-wall pressure vessel steels,such as 0.5Mo,1Cr0.5Mo,2.25Cr1Mo and Hydrogen concentration distributions in the wall of Jan 01,1993 Hydrogen diffusion and solubility in vanadium modified#0183;Int.J.Pres.Ves. Piping 56 (1993) 133-148 Hydrogen Concentration Distributions in the Wall of Pressure Vessels Made of Conventional and V- Modified Steels R.C.Brouwer Shell Research Arnhem,PO Box 40,6800 AA,Arnhem,The Netherlands (Received 24 May 1992; accepted 15 June 1992) ABSTRACT Hydrogen diffusion through the wall of cladded reactors has been modelled both

Hydrogen Trap on the Microstructure of Cr-Mo Type Steels

The hydrogen diffusivity for the 2.25Cr-1Mo-0.25V is lower than 2.25Cr-1Mo due to its higher carbide precipitation.At aged conditions TDS on samples cathodically charged with hydrogen showed an increase on the hydrogen trapping capacity for 2.25Cr-1Mo and a reduction for the vanadium modified steel,compared with the as-received state.Hydrogen Trap on the Microstructure of Cr-Mo Type Steels The hydrogen diffusivity for the 2.25Cr-1Mo-0.25V is lower than 2.25Cr-1Mo due to its higher carbide precipitation.At aged conditions TDS on samples cathodically charged with hydrogen showed an increase on the hydrogen trapping capacity for 2.25Cr-1Mo and a reduction for the vanadium modified steel,compared with the as-received state.Hydrogen Solubility - an overview ScienceDirect TopicsHydrogen and oxygen solubility and diffusivity in perfluorinated ion-exchange polymers used as SPE in state-of-art PEM water electrolyzers are adequately low and gas cross-permeation during operation (hydrogen diffusion across the membrane from cathode to anode and oxygen diffusion from anode to cathode) can be neglected.This is true only when

Hydrogen Diffusivity and Electrolyte Permeability of the

Nov 30,2019 Hydrogen diffusion and solubility in vanadium modified#0183;The diffusion coefficient of hydrogen in KOH is reported as a function of molarity and temperature,26 while data for the hydrogen solubility in KOH could only be found for 30 Hydrogen diffusion and solubility in vanadium modified#176;C.27 Based on these reported values,the hydrogen diffusivity in KOH was calculated for 30 Hydrogen diffusion and solubility in vanadium modified#176;C for the different KOH concentrations used in this study.Hydrogen Diffusion,Solubility,and Water Uptake in Dow's Hydrogen gas diffusion coefficients and solubilities as well as water uptake values are reported for Dow's short-side-chain perfluoro-sulfonic and -carboxylic membranes of different equivalent weight (EW).The diffusion coefficients and solubilities were determined with an electrochemical test cell.Hydrogen solubility decreases with increasing EW in the lower EW range and tends to level off Hiroshi Yukawa's research works Nagoya University Hiroshi Yukawa's 130 research works with 1,994 citations and 3,396 reads,including Analysis for Reverse Temperature Dependence of Hydrogen Permeability through Pd-X (X = Y,Ho,Ni) Alloy

HYDROGEN SOLUBILITY IN ZIRCONIUM ALLOYS (Journal

An indirect method,an isopiestic solubility technique,was employed to measure the hydrogen equilibrium pressures for the vanadium alloys in the range 223 to 473 K.In all the alloys studied,the reaction of hydrogen with the metal phase was exothermic and hydrogen followed Sieverts' law over more a considerable range of hydrogen concentration.First-principles study on the mechanical,thermal 1 day ago Hydrogen diffusion and solubility in vanadium modified#0183;Studying hydrogen behavior in alloys and the mechanical properties of alloys are essential to various practical uses,such as separation membranes,asEffect of aging on hydrogen diffusion and trapping inThe vanadium-rich carbides also showed to be more effective to trap hydrogen in the microstructure of Cr-Mo steels.The hydrogen diffusivity in the CrMoV steels was lower than in CrMo steels and hydrogen solubility was higher for CrMoV steels.Keywords Hydrogen attack,carbide evolution,interfaces,synchrotron source X-ray diffraction,

Diffusion of oxygen and hydrogen in aqueous potassium

May 01,2002 Hydrogen diffusion and solubility in vanadium modified#0183;Modeling Self-diffusion in Multicomponent Aqueous Electrolyte Systems in Wide Concentration Ranges.Industrial Engineering Chemistry Research 1998,37 (7) ,2878-2888.DOI 10.1021/ie980001o.Ping Han and,David M.Bartels.Temperature Dependence of Oxygen Diffusion inDiffusion and Solubility of Hydrogen in Single Crystals of For pure nickel the diffusion coefficient is D=(5.22 Hydrogen diffusion and solubility in vanadium modified#177;0.18) Hydrogen diffusion and solubility in vanadium modified#215;10 3 exp [(9.56 Hydrogen diffusion and solubility in vanadium modified#177;0.04) kcal /RT] cm 2 sec 1 and the solubility in atom fraction H/Ni is S=(3.26 Hydrogen diffusion and solubility in vanadium modified#177;0.17) Hydrogen diffusion and solubility in vanadium modified#215;10 3 exp [(3.60 Hydrogen diffusion and solubility in vanadium modified#177;0.06) kcal /RT].The nickelvanadium alloy is more permeable to hydrogen because of a lower heat of solution of hydrogen (2.09 Hydrogen diffusion and solubility in vanadium modified#177;0.05 kcal/mole) in Diffusion and Solubility of Hydrogen in Single Crystals of A method of obtaining very precise data on the solubility and diffusion of hydrogen in single crystals of metals is described.Results for the permeability,solubility,and diffusivity of hydrogen in pure nickel and a nickel 4.4 at.% vanadium alloy are presented.For pure nickel the diffusion coefficient is D=(5.22 Hydrogen diffusion and solubility in vanadium modified#177;0.18) Hydrogen diffusion and solubility in vanadium modified#215;103exp [(9.56 Hydrogen diffusion and solubility in vanadium modified#177;0.04) kcal/RT] cm2sec1 and the solubility

Diffusion and Solubility of Hydrogen in Single Crystals of

A method of obtaining very precise data on the solubility and diffusion of hydrogen in single crystals of metals is described.Results for the permeability,solubility,and diffusivity of hydrogen in pure nickel and a nickel 4.4 at.% vanadium alloy are presented.For pure nickel the diffusion coefficient is D=(5.22 Hydrogen diffusion and solubility in vanadium modified#177;0.18) Hydrogen diffusion and solubility in vanadium modified#215;103exp [(9.56 Hydrogen diffusion and solubility in vanadium modified#177;0.04) kcal/RT] cm2sec1 and the solubility Diffusion and Solubility of Hydrogen in Single Crystals of A method of obtaining very precise data on the solubility and diffusion of hydrogen in single crystals of metals is described.Results for the permeability,solubility,and diffusivity of hydrogen in pure nickel and a nickel -4.4 at.% vanadium alloy are presented.For pure nickel the diffusion coefficient is D=(5.22 Hydrogen diffusion and solubility in vanadium modified#177;0.18) Hydrogen diffusion and solubility in vanadium modified#215;10 -3 exp [-(9.56 Hydrogen diffusion and solubility in vanadium modified#177;0.04) kcal/RT] cm Hydrogen diffusion and solubility in vanadium modifiedlt;SUP Hydrogen diffusion and solubility in vanadium modifiedgt;2 Hydrogen diffusion and solubility in vanadium modifiedlt;/SUP Hydrogen diffusion and solubility in vanadium modifiedgt;sec Hydrogen diffusion and solubility in vanadium modifiedlt;SUP Hydrogen diffusion and solubility in vanadium modifiedgt;-1 Hydrogen diffusion and solubility in vanadium modifiedlt;/SUP Hydrogen diffusion and solubility in vanadium modifiedgt; and Concentration dependence of hydrogen diffusion inNov 24,2016 Hydrogen diffusion and solubility in vanadium modified#0183;The chemical diffusion coefficient of hydrogen in a 50 nm thin film of vanadium (0 0 1) is measured as a function of concentration and temperature,well above the known phase boundaries.Arrhenius analysis of the tracer diffusion constants reveal large changes in the activation energy with concentration from 0.10 at 0.05 in H V 1 to 0.5 eV

Cited by 360Publish Year 1969Author Ewald Veleckis,Russell Keith EdwardsEffects of vanadium precipitates on hydrogen trapping

Sep 06,2018 Hydrogen diffusion and solubility in vanadium modified#0183;In these cases,the hydrogen diffusion rate decreases ,,,.According to our results,the ability to accommodate H atoms showed an upward trend with increasing of vanadium content,as shown in Table 2.However,the concentration of soluble hydrogen c 0 in V1 steel was the lowest.This was attributed to the presence of the least number of nano Cited by 20Publish Year 2018Author Longfei Li,Bo Song,Jin Cheng,Zhanbing Yang,Zeyun CaiDevelopment of vanadium based hydrogen storage materialThe vanadium based BCC-alloys have been extensively considered for metal hydride based hydrogen compressors worldwide due to their excellent features,i.e.,high hydrogen storage capacity (4 wt Anisotropy of hydrogen diffusion in nickel single crystals Mar 22,2017 Hydrogen diffusion and solubility in vanadium modified#0183;Hydrogen diffusion has an important role in solute-dependent hydrogen embrittlement in metals and metallic alloys.In spite of extensive studies,the complexity of hydrogen diffusion

An Innovative Procedure to Evaluate the Hydrogen Diffusion

A large number of metallic alloys are currently under investigation in the field of hydrogen storage and hydrogen separation membranes.For such applications,the knowledge of the hydrogen diffusion coefficient in the given alloy is of great importance even if its direct measurement is not always easy to perform.In this view,the aim of this work is to describe an innovative procedure able to An Innovative Procedure to Evaluate the Hydrogen Diffusion A large number of metallic alloys are currently under investigation in the field of hydrogen storage and hydrogen separation membranes.For such applications,the knowledge of the hydrogen diffusion coefficient in the given alloy is of great importance even if its direct measurement is not always easy to perform.In this view,the aim of this work is to describe an innovative procedure able to (PDF) Hydrogen diffusion transfer through an asymmetric The hydrogen solubility is found to decrease by the addition of tungsten into vanadium or by increasing the temperature.It is shown that the ductile fracture occurs for V5mol%W alloy even in

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